Faces a sextet of elders (7)
I believe the answer is:
visages
'faces' is the definition.
(visage is a kind of face)
'a sextet of elders' is the wordplay.
'a sextet' becomes 'VI' ('VI' can be a synonym of 'sextet').
'of elders' becomes 'sages' (I can't explain this - if you can you should believe this answer much more).
'vi'+'sages'='VISAGES'
Can you help me to learn more?
(Other definitions for visages that I've seen before include "Human faces" , "Appearances" .)