Failing, join the opposition (6)
I believe the answer is:
defect
'failing' is the definition.
(I've seen this before)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for defect that I've seen before include "Desert - blemish" , "Transfer allegiance to opposition" , "Failing - desert" , "Join opponents in a cause" , "change allegiance" .)