Fancy shop uncovered chili pepper (5)
I believe the answer is:
ancho
'chili pepper' is the definition.
'ancho' can be an answer for 'pepper' (I've seen this before). I am not sure about the 'chili' bit.
'fancy shop uncovered' is the wordplay.
'fancy' becomes 'anc' (I can't justify this - if you can you should believe this answer much more).
'uncovered' indicates the central letters.
The centre of 'shop' is 'ho'.
'anc'+'ho'='ANCHO'
Can you help me to learn more?
(Another definition for ancho that I've seen is " Pepper".)