Favourite part I am hesitating to go after — it requires refinement (9)
I believe the answer is:
petroleum
'hesitating to go after it requires refinement' is the definition.
I can't judge whether this defines the answer.
'favourite part i am' is the wordplay.
'favourite' becomes 'pet' (synonyms).
'part' becomes 'role' (eg a theatrical role).
'i am' becomes 'um' (I can't justify this - if you can you should believe this answer much more).
'pet'+'role'+'um'='PETROLEUM'
Can you help me to learn more?
(Other definitions for petroleum that I've seen before include "It helps in getting things moving" , "Hydrocarbon fuel" , "Hydrocarbon oil" , "Fuel oil" , "Oil well product" .)