Fellow one wouldn't care to have on hand (4)
I believe the answer is:
chap
'fellow' is the definition.
(both can mean a man)
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for chap that I've seen before include "Man; (of skin) turn sore" , "Bloke, fellow" , "Skin crack due to cold - bloke" , "Become raw from cold - fellow" , "Man, sore patch" .)