Find out when positive (9)
I believe the answer is:
ascertain
'find out' is the definition.
('ascertain' can be a synonym of 'find out')
'when positive' is the wordplay.
'when' becomes 'as'.
'positive' becomes 'certain' (similar in meaning).
'as'+'certain'='ASCERTAIN'
(Other definitions for ascertain that I've seen before include "Get to know" , "Establish (the facts)" , "Confirm, make sure" , "Establish, find out" , "Verify" .)