First capital of unified Italy (5)
I believe the answer is:
turin
'first capital of unified italy' is the definition.
(I've seen this in another clue)
This is all the clue.
(Other definitions for turin that I've seen before include "First capital of a united Italy, 1861-65" , "Industrial city in northwest Italy" , "It. city housing shroud" , "City of north Italy" , "City of northwest Italy (with a shroud)" .)