Form of service arranged for the guilty around mid-afternoon (7)
I believe the answer is:
liturgy
'form' is the definition.
(I have seen 'Form of worship ' mean 'liturgy' so perhaps 'form' could also mean 'liturgy')
I don't understand the remainder of the clue.
Can you help me to learn more?
(Other definitions for liturgy that I've seen before include "Standard form of church service" , "Prescribed forms for church services" , "Form of religious service" , "Form of worship" , "Religious rite" .)