Crossword Genius

Free of wrinkles, as a shirt (6)

Ross

I believe the answer is:

ironed

(Other definitions for ironed that I've seen before include "prepared for 23 [WARDROBE] ?" , "flattened" , "Made smooth, shirt or collar" , "Had an evening out" , "Smoothed out wrinkles" .)

I've seen this clue in the Universal.
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