Freed in error, Pierce is a spewer of venom (3-2-5)
I believe the answer is:
fer-de-lance
'spewer of venom' is the definition.
The definition suggests a singular noun which matches the answer.
'freed in error pierce' is the wordplay.
'in error' indicates anagramming the letters.
'pierce' becomes 'lance' (lancing is a kind of piercing).
'freed' is an anagram of 'ferde'.
'ferde'+'lance'='FER-DE-LANCE'
'is a' is the link.
Can you help me to learn more?
(Another definition for fer-de-lance that I've seen is " Venomous American snake".)