From dark heap picked up a sort of acid (6)
I believe the answer is:
nitric
'a sort of acid' is the definition.
(nitric acid)
I don't understand the rest of the clue.
(Other definitions for nitric that I've seen before include "Citrin (anag.)" , "Very corrosive acid type" , "kind of acid" , "Of or containing nitrogen" , "Colourless highly corrosive acid" .)