Gather it’s prayer time (5)
I believe the answer is:
pleat
'gather' is the definition.
(to gather or fold into pleats)
'prayer time' is the wordplay.
'prayer' becomes 'plea' (plea is a kind of prayer).
'time' becomes 't' (abbreviation).
'plea'+'t'='PLEAT'
'it's' is the link.
(Other definitions for pleat that I've seen before include "Fold pressed or stitched into cloth" , "Fold formed in fabric" , "work on skirt?" , "that's tailor-made" , "Fold sewn or pressed into cloth" .)