Gather it's what people may go to church for (5)
I believe the answer is:
amass
'gather' is the definition.
(amass can mean to collect or gather)
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for amass that I've seen before include "store" , "Collect or gather" , "Accumulate, heap up" , "Put together" , "run up?" .)