Gem of an isle? (7)
I believe the answer is:
emerald
I believe this is a double definition.
'gem' is the first definition.
(emerald is a kind of gem)
'an isle?' is the second definition.
(Emerald Isle is an example)
'of' is the link.
(Other definitions for emerald that I've seen before include "Bright green colour" , "Mere lad (anag.)" , "Highly-valued variety of beryl" , "a type employed by the press" , "Shade of green" .)