Generating a stink, but not initially suspicious (4)
I believe the answer is:
iffy
'suspicious' is the definition.
(thesaurus)
I don't understand the remainder of the clue.
Can you help me to learn more?
(Other definitions for iffy that I've seen before include "not kosher" , "Dubious, risky (inf.)" , "Unsure" , "Sixth (RU) Nation" , "Doubtful, not definite" .)