Get together with James (4)
I believe the answer is:
bond
'james' is the definition.
(James Bond is a fictional spy)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for bond that I've seen before include "Valuable asset" , "Fictional agent; link" , "Written promise" , "James ...., fiction's 007" , "Fictional agent; join" .)