Glass maker may disclaim internal breakages (6)
I believe the answer is:
silica
'glass' is the definition.
The answer and definition can be both substances as well as being singular nouns.
Perhaps there's an association between them I don't understand?
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for silica that I've seen before include "Compound in quartz" , "Constituent of sandstone and quartz" , "Hard colourless compound from rocks" , "Eg, quartz" , "Quartz used in the manufacture of glass" .)