Glow of pipe, crack-smoker occasionally managed to get inside (9)
I believe the answer is:
fluoresce
'glow' is the definition.
(I know that fluoresce is a more specific form of the action glow)
'pipe crack-smoker occasionally managed to get inside' is the wordplay.
'pipe' becomes 'flue' (flue is a kind of pipe).
'occasionally' indicates alternate letters (letters taken at regular intervals or occasions).
'managed' indicates an anagram.
'to get inside' is an insertion indicator.
'crack'+'smoker'='cracksmoker'
The alternating letters of 'cracksmoker' are 'rcsoe'.
'rcsoe' with letters rearranged gives 'oresc'.
'flue' placed around 'oresc' is 'FLUORESCE'.
'of' is the link.
(Other definitions for fluoresce that I've seen before include "Emit light when irradiated" , "glow brightly" .)