Go astray or slip (5)
I believe the answer is:
error
'slip' is the definition.
(thesaurus)
'go astray or' is the wordplay.
'go astray' becomes 'err' (I've seen this before**).
'err'+'or'='ERROR'
(Other definitions for error that I've seen before include "Miscarriage of justice" , "Solecism" , "Fallacy, mistake" , "Way of operating" , "Bug" .)