Go-between — a pukka fellow! (5)
I believe the answer is:
agent
'go-between' is the definition.
(I've seen this before)
'a pukka fellow' is the wordplay.
'pukka fellow' becomes 'gent' (synonyms. I am not sure about the 'pukka' bit.).
'a'+'gent'='AGENT'
Can you help me to learn more?
(Other definitions for agent that I've seen before include "Business manager" , "Sales rep" , "Spy - broker" , "Dealer" , "Person acting on behalf of another" .)