Go off regularly on time, always at the start (3)
I believe the answer is:
rot
'go off' is the definition.
(I've seen this before)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for rot that I've seen before include "Drivel" , "Decay or disintegrate" , "Deteriorate" , "Rhubarb" , "Rubbish (colloq.)" .)