Go off to the match unexpectedly? (5)
I believe the answer is:
elope
'match unexpectedly?' is the definition.
(to elope is to secretly marry or 'match')
I can't explain the rest of the clue.
(Other definitions for elope that I've seen before include "Run away together" , "(Lovers) run away" , "leave with lover" , "do a moonlight flit" , "escape" .)