Go with chaps to match as organised by divisions? (14)
I believe the answer is:
departmentally
'as organised by divisions?' is the definition.
I can't tell whether this definition defines the answer.
'go with chaps to match' is the wordplay.
I cannot really understand how this works, but
'go' could be 'depart' (synonyms) and 'depart' is located in the answer.
'chaps' could be 'men' (chap can mean a man) and 'men' is found in the answer.
'match' could be 'tally' (synonyms) and 'tally' is found within the answer.
This accounts for all the letters.
This may be the basis of the clue (or it may be nonsense).
Can you help me to learn more?
(Other definitions for departmentally that I've seen before include "In small groups" , "how a big firm should be organised?" .)