Go with little hesitation to see painter (6)
I believe the answer is:
turner
'painter' is the definition.
(I know that Turner is a painter)
'go with little hesitation' is the wordplay.
'go' becomes 'turn' (as in one's go or turn in a game).
'with' means one lot of letters go next to another.
'little hesitation' becomes 'er' (expression used when hesitating).
'turn'+'er'='TURNER'
'to see' acts as a link.
(Other definitions for turner that I've seen before include "English painter - revolving item?" , "Popular English artist" , "Fighting Temeraire artist" , "Lathe operator and English landscape painter" , "Prize < for artist" .)