Good old precious metal (4)
I believe the answer is:
gold
'precious metal' is the definition.
(gold is a precious metal)
'good old' is the wordplay.
'good' becomes 'g' (abbreviation).
'g'+'old'='GOLD'
(Other definitions for gold that I've seen before include "Mine produces this" , "Element (Au)" , "Thin sheet of precious metal" , "gift from a king" , "Wealth; first prize" .)