Green, natural, timeless (5)
I believe the answer is:
naive
'green' is the definition.
(green can mean naive or innocent)
I don't understand the rest of the clue.
(Other definitions for naive that I've seen before include "Unenlightened" , "Ingenuous, easily deceived" , "Gullible, too trusting" , "Rather too simple and gullible" , "Too trusting and impractical" .)