Guess appropriate power coming from on high (6,5)
I believe the answer is:
divine right
'power coming from on high' is the definition.
(power or authority derived from God)
'guess appropriate' is the wordplay.
'guess' becomes 'divine' (divining is a kind of guessing).
'appropriate' becomes 'right' (similar in meaning).
'divine'+'right'='DIVINE RIGHT'
(Other definitions for divine right that I've seen before include "political doctrine" , "God-given authority" .)