Guess thought to be false (7)
I believe the answer is:
suspect
'guess' is the definition.
(suspecting is a kind of guessing)
I cannot understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for suspect that I've seen before include "Dubious" , "Have qualms about" , "Believe (someone) guilty" , "Presume" , "Believe (something) possible or probable" .)