Guide taking you and me to that woman (5)
I believe the answer is:
usher
'guide' is the definition.
(ushering is a kind of guiding)
'you and me to that woman' is the wordplay.
'you and me' becomes 'us'.
'to that woman' becomes 'her' (I've seen this before).
'us'+'her'='USHER'
'taking' acts as a link.
(Other definitions for usher that I've seen before include "One puts you in your place" , "Show in - escort" , "Minor court official" , "Court or parliamentary official" , "Doorkeeper; shower to seat" .)