Guy with city ways used to wine (6)
I believe the answer is:
townie
'guy with city ways' is the definition.
I can't tell whether this definition defines the answer.
'used to wine' is the wordplay.
'used' indicates an anagram.
'to'+'wine'='towine'
'towine' with letters rearranged gives 'TOWNIE'.
Can you help me to learn more?
(Other definitions for townie that I've seen before include "Urban type" , "citizen" , "No countryman" , "knows little of the country?" , "Inhabitant of an urban area" .)