Having supreme authority appoint entirely new order (15)
I believe the answer is:
plenipotentiary
'having supreme authority' is the definition.
I can't tell whether this definition defines the answer.
'appoint entirely new order' is the wordplay.
'new order' indicates anagramming the letters.
'appoint'+'entirely'='appointentirely'
'appointentirely' anagrammed gives 'PLENIPOTENTIARY'.
Can you help me to learn more?
(Other definitions for plenipotentiary that I've seen before include "Powerful diplomat" , ""The Ambassador"" .)