He seems not to have washed the back of the neck (6)
I believe the answer is:
scruff
'back of the neck' is the definition.
(I've seen this before)
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for scruff that I've seen before include "Unkempt individual" , "One probably wouldn't wash" , "One hardly washing" , "Back of the neck, used to lift cat" , "Back of the neck; untidy person" .)