Head of finance (7)
I believe the answer is:
capital
This clue is a double definition.
'head' is the first definition.
(thesaurus)
'finance' is the second definition.
(thesaurus)
'of' acts as a link.
(Other definitions for capital that I've seen before include "Wellington, say" , "Havana, say" , "source of profit" , "Funds" , "Money available to produce interest" .)