Head off from Australian backwater, perhaps due to unpleasant odour? (4)
I believe the answer is:
reek
'unpleasant odour?' is the definition.
(I know that unpleasant odour can be written as reek)
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for reek that I've seen before include "Does Croagh Patrick smell?" , "Smell of smoke in Kerry?" , "Smell like 12 Across" , "Smell bad" , "Whiff" .)