Heavenly body which rises when hot (7)
I believe the answer is:
mercury
I believe this clue is a double definition.
'heavenly body' is the first definition.
(Mercury is an example)
'which rises when hot' is the second definition.
(mercury rises in a thermometer)
(Other definitions for mercury that I've seen before include "Element, symbol Hg" , "First rock from the Sun - Hg" , "one in distant orbit?" , "Atomic number 80" , "Planet nearest the sun" .)