Heinrich, the hot-headed one (5)
I believe the answer is:
heine
'heinrich the' is the definition.
I can't tell whether this defines the answer.
'hot-headed one' is the wordplay.
'hot' becomes 'h' (abbreviation eg on taps).
'headed one' becomes 'eine' (I am not sure about this - if you are sure you should give a lot more credence to this answer).
'h'+'eine'='HEINE'
Can you help me to learn more?
(Other definitions for heine that I've seen before include "Heinrich -, nineteenth century German poet" , "Heinrich -, Ger. poet" .)