Heroin addict abandoning us for £1 (7)
I believe the answer is:
smacker
'abandoning us for ps1' is the definition.
I can't judge whether this definition defines the answer.
'heroin addict' is the wordplay.
'heroin' becomes 'smack' (synonyms).
'addict' becomes 'er' (I can't justify this - if you can you should give a lot more credence to this answer).
'smack'+'er'='SMACKER'
Can you help me to learn more?
(Other definitions for smacker that I've seen before include "pound" , "Loud kiss -- PS1" , "someone taking part in strike?" , "Loud kiss - GBP1" .)