He's among the greatest ex-champions alive (3)
I believe the answer is:
ali
'he's' is the definition.
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for ali that I've seen before include "Son-in-law to Muhammad" , "US heavyweight boxer" , "Ringmaster" , "Muhammad ... (former fighter)" , "Lepidopterous floater, apian stinger, d. 2016" .)