He's sunny, but not Jim (3)
I believe the answer is:
ray
'he's' is the definition.
I cannot understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for ray that I've seen before include "Beam; flat-bodied fish" , "Gleam" , "bit of sunshine" , "A bright beam or flat fish" , "Narrow beam of light" .)