Hesitate when not quite sober (5)
I believe the answer is:
demur
'hesitate' is the definition.
(I've seen this in another clue)
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for demur that I've seen before include "Hesitate from uncertainty or object" , "Waver" , "'Object, show reluctance (5)'" , "Raise mild objection" , "Hesitation" .)