Hot sweet endlessly served up for associate (6)
I believe the answer is:
hobnob
'for associate' is the definition.
(to hobnob with people is to associate with them)
I don't understand the rest of the clue.
(Other definitions for hobnob that I've seen before include "Mix socially with the biscuit" , "Associate familiarly" , "Associate informally" , "Spend time chatting to a VIP?" , "Socialise informally" .)