I hear, say when to start with the starch! (4)
I believe the answer is:
sago
'the starch' is the definition.
(sago is a kind of starch)
I don't understand the remainder of the clue.
Can you help me to learn more?
(Other definitions for sago that I've seen before include "Type of milk pudding" , "Starchy food as white pudding" , "Edible powdery starch" , "Edible palm starch" , "Starchy pudding cereal" .)