Illegally assist a venture (4)
I believe the answer is:
abet
'illegally assist' is the definition.
(I've seen this in another clue)
'a venture' is the wordplay.
'venture' becomes 'bet' (bet is a kind of venture).
'a'+'bet'='ABET'
(Other definitions for abet that I've seen before include "Incite or encourage" , "Aid in offence" , "Help in wrongdoing" , "Encourage or assist (someone) to commit crime" , "Help a criminal" .)