I'm chattier performing sums? (10)
I believe the answer is:
arithmetic
'sums?' is the definition.
'i'm chattier performing' is the wordplay.
'performing' indicates an anagram.
'im'+'chattier'='imchattier'
'imchattier' anagrammed gives 'ARITHMETIC'.
(Other definitions for arithmetic that I've seen before include "kind of mean" , "Branch of mathematics" , "Calculating" , "Calculation" , "manipulation of figures" .)