In a courtly way, he's like a London Baron (4)
I believe the answer is:
'baron' is the definition.
(thesaurus)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for earl that I've seen before include "Countess his wife" , "Male member of British nobility" , "Rank immediately above viscount" , "British nobleman" , "Essex, say" .)