In agreement immediately about leaving (2,3)
I believe the answer is:
at one
'in agreement' is the definition.
(thesaurus)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for at one that I've seen before include "time to enjoy 21 and 15 [TURKEY and CRACKERS] s?" , "Agreed" , "In agreement" , "in harmony" .)