In hospital, she may have a ward to herself (6)
I believe the answer is:
sister
'in' is the definition.
Both the answer and definition are adjectives. Perhaps you can see a link between them that I don't see?
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for sister that I've seen before include "Close relation" , "Tender" , "Nun's title" , "The nurse in charge" , "Martin --, film director" .)