In practice (without public relations) unsuitably sour or vinegary (6)
I believe the answer is:
acetic
'vinegary' is the definition.
(I've seen this before)
I don't understand the remainder of the clue.
Can you help me to learn more?
(Other definitions for acetic that I've seen before include "Type of acid derived from vinegar" , "Vinegar-like" , "sort of acid" , "Like the acid in vinegar" , "tart" .)