In the Bible, Simon was no saint! (5)
I believe the answer is:
magus
'saint' is the definition.
The answer and definition can be both people as well as being singular nouns.
Perhaps you can see an association between them that I don't see?
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for magus that I've seen before include "Wizard" , "Guru" , "astrologer" , "Sorcerer" , "eg Melchior" .)