Initial letter (5)
I believe the answer is:
alpha
This clue is a double definition.
'initial' is the first definition.
(thesaurus)
'letter' is the second definition.
(NATO phonetic alphabet)
(Other definitions for alpha that I've seen before include "Foreign character" , "Burrowing American rodent" , "letter opener" , "leader in Athens, originally" , "First letter of the Greek alphabet" .)